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Ethanol
Ethanol Production Basics
Download The Handbook for Handling, Storing, and Dispensing E85
FAQ - Ethanol Basics and Myths about Ethanol
What is ethanol?
Ethanol
is ethyl alcohol produced from fermenting grains or other starch or
sugar feedstocks. Fuel ethanol has been ‘de-natured’ with 5% gasoline,
so that it cannot be consumed by people. Most ethanol produced in
America is made from corn: the kernels are ground, cooked in a mash to
convert the starch to sugar, then fermented and distilled into pure
ethyl alcohol. Only the starch is converted to ethanol. The remaining
protein, fat and minerals in the spent grains are fed to cattle. This
‘distillers grain’ is a nutritious feed for animals, and displaces
much of the corn in cattle rations.
Ethanol is:
Non-toxic
Biodegradable
Water soluble
Has higher octane
Contains oxygen
Is heavier than gas
Contains 72% the energy of gas
Conducts electricity (gas does not)
Has an invisible flame
Vapor is more flammable than gas at 32 degrees but less flammable than gas at room temperature
Currently ethanol can be used in two blends – E10 (10% ethanol) and E85 (85% ethanol)
What is cellulosic ethanol?
Cellulosic
ethanol is produced from biomass – crop residues, sawdust, wood chips,
other forestry residue, urban waste wood and yard debris, as well as
energy crops like hybrid poplar, switchgrass and other fast-growing
plants.
There are a few processes to produce cellulosic
ethanol. Furthest along in development are enzymatic processes that use
specially bred fungi and other organisms to break down the cellulose,
hemi-cellulose and lignin of biomass into fermentable sugars. Some
pilot plants are in operation, and the first commercial-scale
production plants are in construction and development.
Myths about Ethanol
Myth: Ethanol consumes more energy than it produces
Fact: Gas has a negative energy balance, ethanol has a positive energy balance
Energy in Energy Out
Ethanol .74 1.0
Gas 1.23 1.0
The production of ethanol has a 34% energy gain, while the production
of gasoline has a 19.5% energy loss, according to a 2004 USDA study. In
June 2004, the U.S. Department of Agriculture determined that the net
energy balance of ethanol production is 1.67 to 1.1. For every 100 BTUs
of energy used to make ethanol, 167 BTUs of ethanol is produced. The
USDA findings have been confirmed by additional studies conducted by
the University of Nebraska and Argonne National Laboratory. These
figures take into account the energy required to plant, grow and
harvest the corn—as well as the energy required to manufacture and
distribute the ethanol.
Myth: Corn ethanol causes food prices to increase
Fact:
Price increases for food have less to do with ethanol or biodiesel
production, than they do with the five fold increase in petroleum price
over the past five years. Several studies have shown that record
petroleum prices, which permeate the entire food system for all types
of food, have added three times the food price impact as biofuels.
U.S. corn ethanol is made from field corn, not corn consumed directly
by humans. The prices farmers receive for corn has a very marginal
effect on retail food prices. There is less than a nickel’s worth of
corn in a box of cornflakes, and less than 2 cents worth of corn syrup
in a can of soda. Eighty percent (80%) of the average retail price of
food is added after it leaves the farm, with about half of that in
labor costs. The foods with the highest price increases in 2007 were
fruits and vegetables which have little to do with biofuels. A
increasing standard of living in China and India, droughts in Australia
and Europe, regional natural disasters/pests/diseases, increases in
labor and fuel costs globally, a declining dollar driving exports, and
corporate profits at retail have all contributed to higher food costs.
Myth: Ethanol uses more carbon than petroleum due to its land use
Fact:
Biofuels have been criticized as a “carbon debt” under the assumption
that for every acre of land dedicated to biofuel crops, another acre of
land must be put into food production elsewhere in the world. Recent
reports assert that increasing production of biofuels in the U.S. is
driving destruction of ecosystems in South America and Asia for food
production and attributes a carbon debt to biofuels from the
clearcutting of rainforests and cultivation of native ecosystems.
This assertion is based on assumptions and models that are not and
cannot be verified. This “secondary land use impacts” assumption
counters all current, verified analyses showing substantial greenhouse
gas emission reductions for biofuels. The assertion is flawed for
several reasons. It inappropriately assigns all of the impact to growth
in biofuels, ignoring the effects of a growing world economy, increased
demand for food, and urban sprawl. It fails to account for advances in
seed and processing technology that are providing greater yields for
each acre of biofuel feedstock. It also ignores the value of the feed
co-products that are produced at today’s biorefineries such as
distillers grain (from corn ethanol plants) and canola and soy meal
(co-products of biodiesel), all of which are used to feed livestock.
By the logic used in these reports, any non-food crop is to blame for
the destruction of ecosystems. A large percentage of land in the U.S.
is planted in seed crops, nursery products, hay, pasture, and farm
forest products. For example, 45% of agriculture production in Oregon
is non-food such as Chris tmas trees, grass seed, and nursery trees. If
one is to argue that a crop used for a biofuel displaces food, then one
has to also accept that a crop grown for anything other than food is
displacing food. Also, every new subdivision or greenfield commercial,
industrial, or residential development would be responsible for
creating a “carbon debt” by taking potential food-producing land out of
production.
From a broad perspective, land use is affected by
many influences, including urbanization, which is eating up millions of
acres of agricultural land per year (at the rate of two acres of
agricultural land being lost to development every minute of every day
). Further, grains are less efficient at nutritional output per acre
than other crops, such as potatoes, which have the highest nutrient and
calorie output per acre of nearly any crop. Yet, not everyone wants to
eat potatoes all the time. Farmers respond to pricing signals from
consumers and from various government incentives -- in all countries
around the world. Biofuels are hardly unique in this sense and singling
them out as a land use focus is folly without looking at the larger
picture of all land use, including urbanization impacts, local/national
land use zoning laws, non-food production of all types, etc.
Productivity increases in U.S. agriculture have enabled farmers to
produce 500% more today than 60 years ago while using less land.
Technology and efficiencies will continue to enable these advances.
Biofuel crops grown in the U.S. are not displacing forests, wetlands,
or other native plants. These are lands that have been farmed for
decades and will continue to be. The mix of crops grown on them changes
in response to market price signals. It is also important to remember
that certain crops grow in certain areas because of soils, rainfall,
and climate. Land use in other nations is complex, but the linkage to
biofuels production is marginal. The increase in soybean acreage in
Brazil is due to China and India ’s growing populations rather than
biofuels.
Corn acreage in the U.S. peaked in 1917 with 116
million acres planted, compared to 93 million acres in 2007. During
that period yields have increased by more than 1 bushel/acre/year, from
29 bushels/acre to 200 bushels/acre. During a time of increased corn
ethanol production, the U.S. is harvesting more than 10 billion bushels
of corn, and exports are rising. In 2007, farmers planted more
additional acreage in corn than all corn used in ethanol production.
U.S. corn ethanol production is not causing a need for increased grain
production in the world.
Myth: Ethanol is worse to the environment than petroleum
Fact:
Every gallon of biofuel produced today requires less land, requires
less water and is less energy intensive than a decade ago, while the
opposite is true for oil production. Every new gallon of oil produced
is more energy intensive and requires more water than before. The
“easy” sources of oil have been found and are being depleted. What is
left are more remote, costlier and more environmentally damaging
nontraditional sources such as Canadian tar sands or Rocky Mountain oil
shale.
Current technologies in agriculture and biofuel
processing have dramatically increased efficiency, lowered inputs, and
help to conserve our soil and water resources (such as direct seed, no
or low till practices). Biofuels have lower greenhouse gas emissions
than fossil fuels and they improve our air quality through lower
tailpipe emissions. Ethanol has replaced MTBE as an oxygenate for
gasoline due to the health impacts of MTBE contaminating groundwater.
Ethanol Benefits
Reduces our dependence on foreign petroleum
Over 60% of our petroleum is imported
In 2007, ethanol reduced oil imports by 228.2 million barrels, saving $16.5 billion from being sent to foreign countries.
Decreases tailpipe emissions, better for the environment
E10 has 30% less carbon monoxide than regular gasoline, 25% less particulate matter
Gasoline contains more than 150 chemicals including numerous toxics and
carcinogens while ethanol is non-toxic and biodegradable
Ethanol replaces toxic additives which prevent fuel system freezing and reduce fuel system deposits while increasing octane
Increases U.S. economic development
The ethanol industry alone accounts for 238,000 jobs, $47.6 billion in GDP and saves consumers $12.3 billion.
Cleaner-burning fuel
Unlike gasoline, ethanol creates no carbon, sulfur, and other residues that often clog combustion chambers and dirty engines.
Ethanol-enriched fuel burns cleaner, does not leave gummy deposits in
fuel systems and helps to keep engines cleaner for optimal performance.
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Oxygenates
Oxygenates are often added to gasoline to add oxygen to the fuel to
improve combustion efficiency and reduce carbon monoxide emissions.
Common oxygenates are ethanol and MTBE.
Oxygenates reduce harmful gasoline emissions by helping create a more
complete combustion process. Ethanol is an eco-friendly alternative to
MTBE (which has serious health and environmental issues).
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Ethanol Fun Facts
Ethanol was first used as a motor fuel in 1826 in an engine that ran on ethanol and turpentine
Henry Ford’s first automobile (late 1880s) was designed to run on pure ethanol
60 million gallons per year of ethanol were used during World War I
56% of all gasoline sold in the U.S. is blended with some percentage of ethanol
1 bushel of corn equals approximately 2.8 gallons of ethanol
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Octane and Ethanol
Octane is a measure of a fuel’s resistance to engine knocking during
combustion in a spark-ignition engine (includes pre-ignition and
detonation). Gasoline cannot be refined higher than about 86 octane
which is insufficient to protect many modern engines from knock-related
problems and damage. Ethanol (108+) has a much higher octane rating
than gasoline, so ethanol-enriched gasoline provides better protection
for your engine. Octane does not measure the power in a fuel.
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Octane
The octane number on the gas pump is called the Anti-Knock Index (AKI).
It is the average of two octane ratings, the Research Octane Number
(RON) and the Motor Octane Number (MON).
RON affects low to medium speed knock and run-on (dieseling).
MON affects high speed, under-load knock.
AKI = (R + M)/2 = Octane Rating
Fuel Typical octane rating
Regular gasoline 87
E10 89
Premium 93
E85 105
Ethanol has a much higher octane rating than gasoline.
Usually higher compression engines need higher octane fuel (as
compression rises, so do the octane requirements). Higher compression
engines also raise cylinder temperatures. Ethanol provides an advantage
for higher compression engines because it is cooler burning.
Ethanol blends increase engine power output while reducing problems with knocking.
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Pre-ignition
Pre-ignition happens when the air/fuel mixture is ignited before the
spark plug fires. Pre-ignition can cause knocking or pinging in an
engine. Things to remember about pre-ignition include:
- Can occur during the compression stroke
- Often results from hot metal or deposits in the combustion chamber
- Can be caused by using a fuel that is too low in octane
Ethanol-enriched gasoline has a higher octane rating and also helps
keep the combustion chamber cooler than straight gasoline. This helps
reduce problems associated with pre-ignition.
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Air-Fuel Ratio
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Stoichiometric
This is the ideal mix of air and fuel for good drivability. Unlike
gasoline, ethanol contains oxygen. This means it has a lower
stoichiometric than that of gasoline. Depending on the ethanol blend, a
somewhat greater amount of fuel must be injected into the engine. Since
1985, domestic cars have had on-board computerized engine control
systems that easily take care of this for blends up to E10.
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The air to fuel ratio varies by fuel and by the load. More fuel is
needed when ethanol is used which provides more power and a
cooler-running engine (ethanol provides a cooler combustion process).
Ethanol and Fuel Economy
Ethanol has less energy (BTUs) than gasoline. However, how this interacts with fuel mileage is more complicated.
Use of E10 ethanol blend in spark-ignited automobile engines has not
affected, and may have improved, fuel economy (miles per gallon) in
recent EPA field studies. This is partly because modern automobile
engines benefit more from the increased octane content in E10 than the
slight energy content reduction. Recently, Volvo has released an E85
Flex Fuel vehicle that produces about the same fuel economy with E85 as
it does with standard unleaded gasoline. This is because the engine has
been optimized to run on both gasoline and E85, unlike most American
vehicles optimized only for gasoline.
Another recent study
(2007 ACE and State of Minnesota) illustrates that non-Flex Fuel
vehicles may get better fuel economy with increased amounts of ethanol
(E20 to E55) as they do in other countries (like Brazil). Lower fuel
economy may still occur in older, carbureted vehicles, especially those
operating at higher elevations. Modern engine controls compensate for
these fuel variations and result in little or no difference in mileage.
Therefore E10 does not affect fuel economy in most newer vehicles. Even
in older vehicles, the mileage is usually only reduced by about 3%.
Tests run on current vehicles show that certain models run optimally on
higher blends of ethanol such as the Toyota Camry on E30 and certain GM
models on E20.
EPA has identified the single largest factor
in fuel economy is driver operation, and that proper operation can
reduce fuel use (and increase fuel economy) by 26%.
Energy comparison (the amount of energy a fuel contains is measured in BTUs)
Fuel British Thermal Units (BTUs or heat energy) per gallon
Gas 114,000
E10 107,000
E85 81,700
Seasonal blends may cause fluctuations in fuel economy as well. Winter
gas may contain only 108,500 BTUs per gallon and the summer blend may
contain up to 117,000 BTUs per gallon.
Flexible Fuel Vehicles
Flexible Fuel Vehicles (FFVs) can use anywhere between 0 and 85% ethanol.
In 2006, there were 5 million Flexible Fuel Vehicles (FFVs) on the road
How do I know if a car is a Flexible Fuel Vehicle?
Go to www.drivingethanol.org
Check the owner’s manual
Look for the E85 label near the gas cap
Higher Blends of Ethanol with Non-FFVs
E85 can potentially corrode certain materials over time. This is NOT a
concern with E10. FFVs have ethanol-compatible parts - in their fuel
tank, fuel lines, fuel fittings and gaskets, and fuel injectors - so
materials compatibility is not an issue.
Can any gas-fueled vehicle be converted to a Flexible Fuel Vehicle?
Yes, but no conversion kit has been EPA-certified except for Flex-Box Smart Kit for fleet vehicles.
What blend level can be used with non-FFVs?
This depends on the model and age of the vehicle. Tests run on current vehicles show that certain models run optimally on higher blends of ethanol such as the Toyota Camry on E30 and certain GM models on E20.
What impact will increased use of ethanol have on air quality?
According
to the Renewable Fuels Association, the use of ethanol significantly
reduces tailpipe emissions of carbon monoxide, an ozone precursor, VOCs
and fine particulates that pose a health threat to children, seniors
and those with respiratory ailments. Importantly, renewable fuels help
to reduce greenhouse gases emitted from vehicles, including carbon
dioxide, methane and other gases that contribute to global warming.
What vehicles can use ethanol?
Any
internal combustion engine can use E-10 (gasoline with 10% ethanol,
also called gasohol) or a lower ethanol blend. Many cars can also use
E-85, and are called ‘flex fuel vehicles’ for their ability to adjust
ignition timing and air intake based on the fuel. E-85 compatible cars
should have a sticker by the gas cap or on the door. See these links
for details: www.e85fuel.com/ and www.fueleconomy.gov/feg/flextech.shtml.
Does ethanol save energy?
Yes.
The Dept of Agriculture and the Dept of Energy have clarified the
controversy caused by one widely publicized study that claimed a
negative energy balance. “The most recent findings show that corn
ethanol fuel is energy efficient and yields an energy output:input
ratio of 1.6 to 1.” This analysis accounts for all non-solar energy
used to grow, harvest and process corn, produce ethanol in modern
facilities, and also the value of the by-product cattle feed.
(See: US Dept of Energy, www.eere.energy.gov/afdc/altfuel/eth_energy_bal.html and US Dept of Agriculture www.usda.gov/oce/reports/energy/net_energy_balance.pdf )
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